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Pucker

usgb/ˈpʌkər/Volume
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Facial ExpressionsPlay
Often used to describe facial expressions, especially lips when showing disapproval or preparing to kiss. SlideHe puckered his brow in concentration.
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Not Always LiteralPlay
Can be used metaphorically to indicate something is not smooth or straightforward. SlideThe negotiation process puckered with unexpected demands.
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Pucker UpPlay
The phrase 'pucker up' is a common informal instruction to prepare for a kiss. SlidePucker up, I'm going to give you a smooch!