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When the cat’s away the mice will play
Metaphorical Mice
This phrase isn't about animals. It metaphorically compares unsupervised people to 'mice' who misbehave. 
Unsupervised Freedom
The 'cat' represents an authority figure. Without them, people feel free to do as they please. 
Not Just Rule Breaking
The phrase can also imply indulging in activities that aren't usually allowed but aren't necessarily bad. 